Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N   总被引：1，自引：0，他引：1  

荣坤波  曾志刚  殷学博  陈帅  王晓媛  齐海燕  马瑶 《海洋学报(英文版)》2018,37(9):67-81

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.  相似文献   

东太平洋地区DSDP573孔始新世末期的微玻璃陨石   总被引：5，自引：1，他引：5  

尹延鸿  万天丰  孙嘉诗 《海洋地质与第四纪地质》2001,21(4):37-42

通过研究 DSDP5 73孔的岩心样品 ,首次在该孔始新世与渐新世的界线地层含金属粘土层中发现了微玻璃陨石 ,且主要富集在其底部。一个样品 (5 g)中最多可达 12粒。这些微玻璃陨石主要呈球形、椭球形。用电子探针测试了其化学成分 ,Si O2 含量为 2 9.6 4%～ 5 8.93%,Al2 O3 为 3.42 %～ 2 0 .96 %,Fe O为 9.98%～ 2 9.5 5 %,Mg O为 4.32 %～ 16 .0 5 %,Ir为 0 .0 6 %～ 0 .81%。总体来说 ,微玻璃陨石的化学成分变化较大 ,可能与靶岩的成分变化较大有关。始新世末期北美微玻璃陨石场的展布方向约为 2 5 0°,这与太平洋板块运动方向改变所需要的矢量变化(2 45°)仅相差 5°,推测很可能是始新世末期陨星的撞击引起了太平洋板块在该时期的运动方向由 NNW突然变为NWW。  相似文献   

东太平洋573孔始新世末渐新世纪地层特征及稀土元素地球化学     

尹延鸿  王玉荣等 《吉林大学学报(地球科学版)》2002,32(1):29-33

根据深海钻探样品分析，对东太平洋地区573孔始新世末渐新世初的地层进行了研究，尤其是研究了其稀土元素地球化学特征。各层球粒陨石标准化值曲线平缓，重稀土相对富集，各层Ce严重亏损（第2层轻度亏损），各层的Eu仅轻度亏损。始新世与渐新世的界线地层含钨粘土层的稀土元素含量明显比其它层含量高得多。此外，该层还富含Fe及指示地外成因的Ni、Co、Ir等元素，且底部富含微玻璃陨石。这些特征说明该含金属粘土层的形成与火山活动有显关系，其底部可能还与陨击作用相联系。从区域地质情况来看，始新世末期有明显的生物灭绝和环境变化，微玻璃陨石广泛发育，说明该时期明显的灾变事件发生。  相似文献   

陆源碎屑沉积作用对化学元素配分的制约——兼论五台地区前寒武纪碎屑沉积岩示踪源区陆壳成分的意义   总被引：1，自引：0，他引：1  

杨忠芳  陈岳龙 《地质论评》1997,43(6):593-600

为探讨粒度分选沉积作用对沉积物化学成分配分的影响,对比研究了五台群中石英岩、长石石英岩、粉砂岩和粘土岩等不同粒度沉积岩的化学成分特征,结果表明:不同粒度沉积岩的主元素及微量元素均具有较大的变化范围,SiO_2与Al_2O_3及TFe_2O_3之间呈线性负相关关系,这种负相关关系还表现在SiO_2与REE,Rb,Sr之间,这种特征可以用石英的稀释作用进行解释;铁族元素Cr,Ni,Co和REE,Rb,Sr等大离子亲石元素与Al_2O_3呈正相关关系,表明这些元素易在富铝的粘土岩中聚积。不同粒度成分沉积岩的稀土  相似文献   

下扬子PTB界线深水相区粘土岩的火山成因研究及其对LPME的指示意义     

廖志伟  胡文瑄  王小林  曹剑  姚素平  万野 《地质学报》2016,90(4):785-800

全球,尤其是特提斯域二叠—三叠纪之交(PTB)剖面中普遍发育火山成因的粘土岩,对理解晚二叠世末生物大灭绝(LPME)的触发机制及相关基础地质问题具有重要意义。本文报道了在华南下扬子区新发现两条深水PTB剖面(皖南牛山和蔡村)的粘土岩工作,包括岩石学、矿物学和全岩地球化学等,填补了区域研究空白。研究结果发现,粘土岩主要由伊利石等粘土矿物,以及石英、岩浆锆石、长石等斑晶矿物组成。在地球化学上具有高K_2O、低Na_2O、相对富集大离子亲石元素(LILE)、相对亏损高场强元素(HFSE)等特征。据此,认为这些粘土岩为火山成因的钾质斑脱岩,其原岩可能为中酸性流纹英安岩,具有弧岩浆作用的源区背景。对比华南其他地区已发现的PTB界线粘土岩,发现它们成因类似,可能来源于古特提斯洋周缘陆陆碰撞,抑或是泛大洋俯冲潘吉亚大陆东缘(包括华南板块)所导致的长英质火山岩浆喷发,且具有多期多源性特点。PTB时期全球活跃的火山岩浆活动(包括镁铁质火山作用和华南地区火山灰所指征的长英质火山作用)可能是导致LPME的主要原因。  相似文献   

四川江油马角坝刺林包剖面二叠-三叠系间粘土岩研究     

邓煜霖  郎兴海  崔志伟  王旭辉  娄渝明  韩鹏 《岩石矿物学杂志》2018,37(3):417-433

二叠-三叠纪之交华南地区普遍发育火山成因的粘土岩,其对于了解二叠纪末大规模火山活动及扬子板块碎屑物质来源具有重要意义。本文对扬子西缘马角坝刺林包剖面飞仙关组底部粘土岩进行了碎屑锆石U-Pb定年及原位Hf同位素测试、X衍射和全岩地球化学分析,以揭示粘土岩的岩石成分及物源信息。镜下特征、X衍射及主量元素特征表明岩石中粘土矿物主要为伊利石,含少量方解石、石英。碎屑锆石年龄显示,特征峰值年龄主要集中在2 615~2 383、1 868~1 328、1 186~778和430~246 Ma,并出现~250 Ma特征高峰,结合原位Hf同位素特征表明锆石与秦岭造山带、华南典型PTB剖面粘土岩及峨眉山大火成岩省具有较高的相似性。同时,通过微量、稀土元素分析发现粘土岩中Zr、Hf、Th、Cr、Co、Ti相对富集,与华南典型PTB粘土岩和峨眉山玄武岩相近,并结合构造背景及锆石特征,综合认为刺林包剖面PTB粘土岩来自于秦岭造山带及龙门山岛链局部剥蚀区、二叠纪末火山活动和峨眉山大火成岩省剥蚀岩体。  相似文献   

Silurian and Devonian systems     

Maxwell R. Banks  E. D. Gill  K. L. Burns 《Australian Journal of Earth Sciences》2013,60(2):177-187

The Ediacara mineral field is situated 30 km W of Beltana on the western margins of the Flinders Ranges, South Australia, and consists of silver‐lead and copper deposits in lower Cambrian carbonate rocks that contain anomalous base‐metal contents throughout the Adelaide Geosyncline. The lower Cambrian rocks, which consist of the basal Parachilna Formation and overlying Ajax Limestone, rest disconformably on the Precambrian, and at Ediacara occupy a shallow N‐S elongate syncline near the hinge zone of the Adelaide Geosyncline. The main primary ore minerals of the silver‐lead mineralization are galena and pyrite, with very minor chalcopyrite and sphalerite, and rare tetrahedrite and pearceite. The gangue consists mainly of silica (both chalcedony and quartz), with minor dolomite and rare barite. The mineralization is stratabound and occurs in conformable zones, the lowest of which commences about 30–50 m above the base of the Cambrian sequence. The host to the silver‐lead mineralization, the Ajax Limestone, can be subdivided into three units which represent a set of lithologies, structures and organic traces indicative of a shallow near‐shore carbonate environment. The silver‐lead mineralization is mainly present in sandy and laminated dolomites which were deposited in an environment ranging from sub‐tidal to bar and channel and tidal flat, respectively. Four types of mineralization have been recognized; disseminated sulphides of syngenetic and/or diagenetic origin and epigenetic concentrations along stylolites, in veins and as breccia fillings. Post‐depositional solution activity has affected a large proportion of the carbonate sequence. The effects of this activity range from stylolites through stylobreccias to solution collapse breccias. The epigenetic concentrations of mineralizations have apparently been formed by the remobilization of the disseminated sulphides during solution activity. The ore and gangue minerals of the epigenetic mineralization display both euhedral forms and distinct colloform banding, and framboidal textures have also been observed in both pyrite and galena. There is evidence of repeated episodic precipitation and no simple paragenetic sequence can be recognized. Fluid inclusions in silica and dolomite associated with the epigenetic mineralization have homogenization temperatures of 159 to 199°C and freezing temperatures that indicate the fluids to be saline brines containing NaCl with CaCl₂ and/or MgCl₂. Sulphur isotope analyses show a range of 8³⁴S values from ‐12.5 to +8.6 per mil, with no evidence of significant differences between the four types of mineralization. The data suggest deposition of the disseminated sulphides as a result of biological reduction of seawater sulphate in a system partially open with respect to sulphate supply. Subsequent remobilization of sulphides apparently involved little or no sulphur isotope fractionation. The Ediacara silver‐lead deposits have many features in common with Mississippi Valley‐type lead‐zinc deposits and appear to have similarities in terms of genesis, in that the epigenetic mineralization has been formed as a result of post‐depositional solution activity during diagenesis in a sedimentary basin. The scale of transport of the metals deposited as the epigenetic mineralization at Ediacara appears, however, to have been very much less than that of the metals in other Mississippi Valley‐type deposits.  相似文献   

The N663 stope experiment at Mount Isa Mine     

R. W. Greenelsh 《Geotechnical and Geological Engineering》1985,3(3):183-194

Summary Factors affecting the stability of a trial open stope at a depth of 1000 m in fissile foot wall and hanging wall shales are discussed. A combination of systematic support using cable dowels, and reduced disturbance from blasting using low density explosives and single ring firing, allowed successful completion of the stope.  相似文献   

湖北兴山大峡口浅海相二叠系-三叠系界线附近粘土岩研究   总被引：2，自引：0，他引：2  

张素新  赵来时  童金南  杨浩 《矿物岩石》2007,27(3):94-100

利用X射线衍射、扫描电镜、能谱等鉴定分析方法,对湖北兴山大峡口剖面二叠系—三叠系界线附近的8层粘土岩研究发现,各层粘土岩中的主要粘土矿物均为伊/蒙混层矿物,并且各层中均含有数量不等的六方双锥石英和黄铁矿,非粘土矿物为石膏,个别层位中还含有粘土微球粒。该8层粘土岩均为火山物源成因,联系相应的火山事件记录表明该地区在二叠系—三叠系之交经历了多次火山活动。这些火山事件与同时段牙形石的绝灭和延缓复苏呈现一致性。频繁的火山活动是造成二叠纪—三叠纪之交生物及生态系重大转折的主导事件之一。  相似文献   

Indirect estimation of the clay content of clay-rocks using acoustic measurements: New insights from the Montiers-sur-Saulx deep borehole (Meuse,France)     

《Marine and Petroleum Geology》2014

This work benefited from a comprehensive set of logging and mineralogical data that was acquired from the 2-km-deep EST433 borehole of Montiers-sur-Saulx (Meuse, France). A multiple linear regression analysis was performed on three sets of data: (a) sonic data (P- and S-wave velocities), (b) total combinable magnetic resonance (TCMR) porosity data, and (c) X-ray diffraction (XRD) data. The analysis was performed to estimate the clay content in the Callovo-Oxfordian (COx) claystone and other clay-rocks of the stratigraphic column. The inferred statistical relationships were compared to results obtained from a conventional spectral gamma ray (GR) approach.The results indicate that simple linear regressions using only elastic wave velocities (a) accounted for more than 81% of the vertical variability of the clay content in the COx formation (i.e., coefficient regression R² values greater than 81%) and (b) enable the estimation of clay content with the same accuracy as the spectral GR approach. Both approaches, our acoustic regressions and spectral GR methodology, provide estimate errors that are within the range of uncertainties associated with the XRD analysis applied. Moreover, using the whole set of XRD data showed that the elastic wave velocities and the TCMR porosity as explanatory variables are better predictors of total clay content than swelling clay mineral content.Blind estimations of clay content were performed using data acquired in clay-rocks from the same stratigraphic column and in the COx formation located a few kilometers distant in the EST423 borehole. The results demonstrated that the established regressions must be used with caution when vertically and horizontally extrapolating the estimated clay content. This difficulty is partly explained by the influence of the microstructure of the studied clay-rocks, which was insufficiently taken into account via the petrophysical variables considered in this work.  相似文献